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Most macroscopic inorganic solids are polycrystalline, including almost all metals, ceramics, ice, rocks, etc.

Other less exotic methods of crystallization may be used, depending on the physical properties of the substance, including hydrothermal synthesis, sublimation, or simply solvent-based crystallization.

Large single crystals can be created by geological processes.

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Other crystalline rocks, the metamorphic rocks such as marbles, mica-schists and quartzites, are recrystallized.

This means that they were at first fragmental rocks like limestone, shale and sandstone and have never been in a molten condition nor entirely in solution, but the high temperature and pressure conditions of metamorphism have acted on them by erasing their original structures and inducing recrystallization in the solid state Specific industrial techniques to produce large single crystals (called boules) include the Czochralski process and the Bridgman technique.

A crystal structure (an arrangement of atoms in a crystal) is characterized by its unit cell, a small imaginary box containing one or more atoms in a specific spatial arrangement.

The unit cells are stacked in three-dimensional space to form the crystal.

The process of crystal formation via mechanisms of crystal growth is called crystallization or solidification. For example, when liquid water starts freezing, the phase change begins with small ice crystals that grow until they fuse, forming a polycrystalline structure.

In the final block of ice, each of the small crystals (called "crystallites" or "grains") is a true crystal with a periodic arrangement of atoms, but the whole polycrystal does not have a periodic arrangement of atoms, because the periodic pattern is broken at the grain boundaries.

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